| Min | Event | Player | Team | Detail | Ref call |
|---|---|---|---|---|---|
| 5' | Penalty | Ivan Barbero | Arouca | Penalty confirmed | — |
| 7' | Penalty | I. Barbero | Arouca | Penalty | — |
| 22' | Yellow | Javi Sánchez | Arouca | Yellow Card | — |
| 45' | Yellow | Ivan Barbero | Arouca | Yellow Card | — |
| 48' | Yellow | Hyun-ju Lee | Arouca | Yellow Card | — |
| 50' | Goal | R. Rios | Benfica | Normal Goal | — |
| 59' | Yellow | Richard Ríos | Benfica | Yellow Card | — |
| 59' | Yellow | António Silva | Benfica | Yellow Card | — |
| 77' | Yellow | Pablo Gozálbez | Arouca | Yellow Card | — |
| 80' | Yellow | Ignacio de Arruabarrena | Arouca | Yellow Card | — |
| 90' | Goal | F. Ivanovic | Benfica | Normal Goal | — |
| 90' | Yellow | Tomás Araújo | Benfica | Yellow Card | — |
| 90' | Red | Amar Dedić | Benfica | Red Card | — |
| 90' | Red | Alfonso Trezza | Arouca | Red Card | — |
| 90' | Yellow | Vangelis Pavlidis | Benfica | Yellow Card | — |
| 90' | Yellow | Gianluca Prestianni | Benfica | Yellow Card | — |
| 90' | Yellow | Anatoliy Trubin | Benfica | Yellow Card | — |