| Min | Event | Player | Team | Detail | Ref call |
|---|---|---|---|---|---|
| 22' | Yellow | Andrei Rațiu | Rayo Vallecano | Yellow Card | — |
| 23' | Yellow | Unai López | Rayo Vallecano | Yellow Card | — |
| 64' | Penalty | Oihan Sancet | Athletic Club | Penalty confirmed | — |
| 66' | Penalty | O. Sancet | Athletic Club | Penalty | — |
| 69' | Yellow | Álvaro García | Rayo Vallecano | Yellow Card | — |
| 79' | Yellow | Josep Chavarría | Rayo Vallecano | Yellow Card | — |