| Min | Event | Player | Team | Detail | Ref call |
|---|---|---|---|---|---|
| 51' | Yellow | Raúl de Tomás | Rayo Vallecano | Yellow Card | — |
| 55' | Yellow | Rubén Alcaraz | Cadiz | Yellow Card | — |
| 58' | Yellow | Alejandro Catena | Rayo Vallecano | Yellow Card | — |
| 59' | Yellow | Alfonso Espino | Cadiz | Yellow Card | — |
| 74' | Goal | Sergi Guardiola | Cadiz | Normal Goal | — |
| 90' | Yellow | Radamel Falcao | Rayo Vallecano | Yellow Card | — |
| 90' | Red | Alejandro Catena | Rayo Vallecano | Red Card | — |
| 90' | Yellow | Alejandro Catena | Rayo Vallecano | Yellow Card | — |
| 90' | Yellow | Gonzalo Escalante | Cadiz | Yellow Card | — |