| Min | Event | Player | Team | Detail | Ref call |
|---|---|---|---|---|---|
| -5' | Yellow | Iago Aspas | Celta Vigo | Yellow Card | — |
| 40' | Goal | S. Carreira | Celta Vigo | Normal Goal | — |
| 44' | Yellow | Hugo Álvarez | Celta Vigo | Yellow Card | — |
| 54' | Penalty | B. Zaragoza | Celta Vigo | Penalty | — |
| 58' | Yellow | Hugo Sotelo | Celta Vigo | Yellow Card | — |
| 58' | Yellow | Gerard Gumbau | Rayo Vallecano | Yellow Card | — |
| 59' | Yellow | Carlos Martín | Rayo Vallecano | Yellow Card | — |
| 65' | Var | Nobel Mendy | Rayo Vallecano | Card upgrade | — |
| 66' | Yellow | Óscar Mingueza | Celta Vigo | Yellow Card | — |
| 66' | Yellow | Isi Palazón | Rayo Vallecano | Yellow Card | — |
| 66' | Red | Nobel Mendy | Rayo Vallecano | Red Card | — |
| 79' | Goal | J. Rueda | Celta Vigo | Normal Goal | — |