| Min | Event | Player | Team | Detail | Ref call |
|---|---|---|---|---|---|
| 16' | Yellow | Unai López | Rayo Vallecano | Yellow Card | — |
| 31' | Yellow | Pol Lozano | Espanyol | Yellow Card | — |
| 39' | Penalty | R. Fernandez Jaen | Espanyol | Penalty | — |
| 42' | Yellow | Nobel Mendy | Rayo Vallecano | Yellow Card | — |
| 50' | Yellow | Gerard Gumbau | Rayo Vallecano | Yellow Card | — |
| 63' | Yellow | Óscar Valentín | Rayo Vallecano | Yellow Card | — |
| 64' | Yellow | Unai López | Rayo Vallecano | Yellow Card | — |
| 64' | Red | Unai López | Rayo Vallecano | Red Card | — |
| 67' | Penalty | Charles Pickel | Espanyol | Penalty cancelled | — |
| 73' | Yellow | Josep Chavarría | Rayo Vallecano | Yellow Card | — |
| 76' | Yellow | Urko González | Espanyol | Yellow Card | — |
| 77' | Yellow | Tyrhys Dolan | Espanyol | Yellow Card | — |
| 84' | Var | Kike García | Espanyol | Goal cancelled | — |
| 87' | Yellow | Tyrhys Dolan | Espanyol | Yellow Card | — |
| 87' | Red | Tyrhys Dolan | Espanyol | Red Card | — |
| 87' | Yellow | Augusto Batalla | Rayo Vallecano | Yellow Card | — |
| 90' | Yellow | Iván Balliu | Rayo Vallecano | Yellow Card | — |