| Min | Event | Player |
|---|
| Team |
|---|
| Detail |
|---|
| Ref call |
|---|
| 29' | Yellow | Nobel Mendy | Rayo Vallecano | Yellow Card | — |
| 53' | Red | Ilyas Chaira | Oviedo | Red Card | — |
| 73' | Yellow | Nacho Vidal | Oviedo | Yellow Card | — |
| 80' | Yellow | Isi Palazón | Rayo Vallecano | Yellow Card | — |
| 90' | Red | Pathé Ismaël Ciss | Rayo Vallecano | Red Card | — |