| Min | Event | Player | Team | Detail | Ref call |
|---|---|---|---|---|---|
| 27' | Yellow | Yarek Gasiorowski | PSV Eindhoven | Yellow Card | — |
| 30' | Yellow | Joey Veerman | PSV Eindhoven | Yellow Card | — |
| 31' | Goal | S. McTominay | Napoli | Normal Goal | — |
| 35' | Goal | A. Buongiorno | PSV Eindhoven | Own Goal | — |
| 38' | Goal | I. Saibari | PSV Eindhoven | Normal Goal | — |
| 42' | Yellow | Leonardo Spinazzola | Napoli | Yellow Card | — |
| 54' | Goal | D. Man | PSV Eindhoven | Normal Goal | — |
| 70' | Yellow | Ismael Saibari | PSV Eindhoven | Yellow Card | — |
| 76' | Red | Lorenzo Lucca | Napoli | Red Card | — |
| 80' | Goal | D. Man | PSV Eindhoven | Normal Goal | — |
| 86' | Goal | S. McTominay | Napoli | Normal Goal | — |
| 87' | Goal | R. Pepi | PSV Eindhoven | Normal Goal | — |
| 89' | Goal | C. Driouech | PSV Eindhoven | Normal Goal | — |
| 90' | Yellow | Couhaib Driouech | PSV Eindhoven | Yellow Card | — |