| Min | Event | Player | Team | Detail | Ref call |
|---|---|---|---|---|---|
| 40' | Yellow | Dani Parejo | Villarreal | Yellow Card | — |
| 56' | Goal | Raúl de Tomás | Rayo Vallecano | Normal Goal | — |
| 59' | Yellow | Alfonso Pedraza | Villarreal | Yellow Card | — |
| 63' | Goal | Isi Palazón | Rayo Vallecano | Normal Goal | — |
| 65' | Yellow | Óscar Valentín | Rayo Vallecano | Yellow Card | — |
| 68' | Yellow | Raúl de Tomás | Rayo Vallecano | Yellow Card | — |
| 70' | Yellow | Giovani Lo Celso | Villarreal | Yellow Card | — |
| 83' | Goal | G. Lo Celso | Villarreal | Normal Goal | — |
| 90' | Yellow | Alejandro Catena | Rayo Vallecano | Yellow Card | — |
| 90' | Yellow | Nicolas Jackson | Villarreal | Yellow Card | — |