| Min | Event | Player | Team | Detail | Ref call |
|---|---|---|---|---|---|
| 9' | Goal | Santi Comesaña | Rayo Vallecano | Normal Goal | — |
| 23' | Yellow | Óscar Valentín | Rayo Vallecano | Yellow Card | — |
| 27' | Yellow | Thierry Correia | Valencia | Yellow Card | — |
| 36' | Yellow | Justin Kluivert | Valencia | Yellow Card | — |
| 81' | Yellow | Ivan Balliu | Rayo Vallecano | Yellow Card | — |
| 82' | Penalty | J. Kluivert | Valencia | Penalty | — |
| 90' | Yellow | Alejandro Catena | Rayo Vallecano | Yellow Card | — |