| Min | Event | Player | Team | Detail | Ref call |
|---|---|---|---|---|---|
| 13' | Yellow | Luiz Júnior | Villarreal | Yellow Card |
| — |
| 18' | Yellow | Alberto Reina | Oviedo | Yellow Card | — |
| 27' | Yellow | Alberto Reina | Oviedo | Yellow Card | — |
| 27' | Red | Alberto Reina | Oviedo | Red Card | — |
| 29' | Goal | Etta Eyong | Villarreal | Normal Goal | — |
| 36' | Goal | P. Gueye | Villarreal | Normal Goal | — |