| Min | Event | Player | Team | Detail | Ref call |
|---|---|---|---|---|---|
| 3' | Yellow | David García | Osasuna | Yellow Card | — |
| 16' | Yellow | Juan Cruz | Osasuna | Yellow Card | — |
| 22' | Red | Sergio Herrera | Osasuna | Red card cancelled | — |
| 36' | Yellow | Chimy Ávila | Osasuna | Yellow Card | — |
| 68' | Yellow | Lucas Torró | Osasuna | Yellow Card | — |
| 71' | Yellow | Hugo Duro | Valencia | Yellow Card | — |
| 74' | Goal | J. Kluivert | Valencia | Normal Goal | — |
| 87' | Yellow | Aimar Oroz | Osasuna | Yellow Card | — |
| 87' | Red | Aimar Oroz | Osasuna | Red card cancelled | — |
| 89' | Penalty | Thierry Correia | Valencia | Penalty confirmed | — |
| 90' | Yellow | José Luis Gayà | Valencia | Yellow Card | — |